The Resource Advances in inorganic chemistry, Volume 65, Homogeneous catalysis, edited by Rudi van Eldik, Colin D. Hubbard, (electronic resource )

Advances in inorganic chemistry, Volume 65, Homogeneous catalysis, edited by Rudi van Eldik, Colin D. Hubbard, (electronic resource )

Label
Advances in inorganic chemistry, Volume 65, Homogeneous catalysis
Title
Advances in inorganic chemistry
Title number
Volume 65
Title part
Homogeneous catalysis
Statement of responsibility
edited by Rudi van Eldik, Colin D. Hubbard
Contributor
Subject
Genre
Language
  • eng
  • eng
Summary
The Advances in Inorganic Chemistry series present timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bio-inorganic to solid state studies. This acclaimed serial features reviews written by experts in the field and serves as an indispensable reference to advanced researchers. Each volume contains an index, and each chapter is fully referenced. * Features comprehensive reviews on the latest developments * Includes contributions from leading experts in the field * Serves as an indispensable reference t
Is Subseries of
Cataloging source
MiAaPQ
Dewey number
546
Illustrations
illustrations
Index
index present
Language note
English
LC call number
QD505
LC item number
.A3865 2013
Literary form
non fiction
Nature of contents
  • dictionaries
  • bibliography
http://library.link/vocab/relatedWorkOrContributorName
  • Eldik, Rudi van
  • Hubbard, Colin D
Series statement
Advances in inorganic chemistry
Series volume
65
http://library.link/vocab/subjectName
  • Chemistry, Inorganic
  • Catalysis
Label
Advances in inorganic chemistry, Volume 65, Homogeneous catalysis, edited by Rudi van Eldik, Colin D. Hubbard, (electronic resource )
Instantiates
Publication
Note
Description based upon print version of record
Bibliography note
Includes bibliographical references and index
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Front Cover; Homogeneous Catalysis; Copyright; Contents; Contributors; Preface; Chapter One: Homogeneous Multicopper Catalysts for Oxidation and Hydrocarboxylation of Alkanes; 1. Introduction; 2. Multicopper Complexes and Coordination Polymers; 3. Oxidation of Alkanes; 4. Hydrocarboxylation of Alkanes; 5. Final Comments; Acknowledgments; References; Chapter Two: Homogeneous Catalytic Olefin Epoxidation with Molybdenum Complexes; 1. Introduction; 2. Organomolybdenum Complexes Bearing a Mo-C σ-Bond; 3. η5-Cyclopentadienyl Molybdenum Complexes
  • 3.1. η5-Cyclopentadienyl molybdenum complexes bearing a halide or alkyl ligand3.2. Chiral organomolybdenum complexes; 3.3. Ansa-bridged η5-cyclopentadienyl molybdenum complexes; 3.4. Dinuclear η5-cyclopentadienyl molybdenum complexes; 3.5. η5-Cyclopentadienyl molybdenum complexes with NHC spectator ligands; 3.6. η5-Cyclopentadienyl molybdenum complexes with a π-allyl ligand; 4. Summary and Outlook; References; Chapter Three: Manganese and Iron Bleaching and Oxidation Catalysts; 1. Introduction; 2. Epoxidation of Alkenes; 2.1. General
  • 2.2. Manganese complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane ligands3. Cellulosic Bleaching; 3.1. Detergent applications; 3.1.1. General; 3.1.2. Activation of hydrogen peroxide by transition-metal complexes; 3.1.3. Stain bleaching by manganese complexes with 1,4,7-triazacyclononane-based ligands; 3.2. Raw cotton bleaching; 3.2.1. General; 3.2.2. Manganese complexes containing 1,4,7-triazacyclononane ligands; 3.3. Wood pulp bleaching; 3.3.1. General; 3.3.2. Bleach catalysts; 4. Paint Drying; 5. Conclusions; References
  • Chapter Four: Green Challenges of Catalysis via Iron(IV)oxo and Iron(V)oxo Species1. Introduction; 2. Iron(IV)oxo Complexes; 3. A Race for Iron(V)oxo Molecules; 3.1. Spectral characterization of iron(V)oxo compounds; 3.2. Reactivity of iron(V)oxo complexes; 4. Oxidative Catalysis in Aqueous Environment; 4.1. Guiding strategies; 4.2. Catalyzed oxidations by hydrogen peroxide in water; 4.3. Second generation of TAML activators; 4.4. Problems associated with environmentally relevant catalysis; 4.5. Novel applications of TAML activators
  • 5. Back to Nature or Metal-Organic Framework Instead of a Protein Coat?5.1. Protection of oxidation catalyst by biomolecules; 5.2. Metal-organic materials; 6. Concluding Remarks; Acknowledgments; References; Chapter Five: Manganese Compounds as Versatile Catalysts for the Oxidative Degradation of Organic Dyes; 1. Introduction; 2. Metal Ion-Catalyzed Oxidative Dye Degradation by H2O2; 2.1. General observations; 2.2. Complex formation between bicarbonate and Mn(II); 2.3. Complex formation between dye and Mn(II); 2.4. Mn(II)+H2O2/HCO3-: Intermediates in the absence of dye substrate
  • 2.5. Kinetic investigations
Dimensions
unknown
Extent
1 online resource (341 p.)
Form of item
online
Isbn
9780124046405
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (EBL)1111845
  • (OCoLC)827210726
  • (SSID)ssj0000912399
  • (PQKBManifestationID)11554271
  • (PQKBTitleCode)TC0000912399
  • (PQKBWorkID)11006024
  • (PQKB)10862386
  • (MiAaPQ)EBC1111845
  • (EXLCZ)992670000000325410
Label
Advances in inorganic chemistry, Volume 65, Homogeneous catalysis, edited by Rudi van Eldik, Colin D. Hubbard, (electronic resource )
Publication
Note
Description based upon print version of record
Bibliography note
Includes bibliographical references and index
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Front Cover; Homogeneous Catalysis; Copyright; Contents; Contributors; Preface; Chapter One: Homogeneous Multicopper Catalysts for Oxidation and Hydrocarboxylation of Alkanes; 1. Introduction; 2. Multicopper Complexes and Coordination Polymers; 3. Oxidation of Alkanes; 4. Hydrocarboxylation of Alkanes; 5. Final Comments; Acknowledgments; References; Chapter Two: Homogeneous Catalytic Olefin Epoxidation with Molybdenum Complexes; 1. Introduction; 2. Organomolybdenum Complexes Bearing a Mo-C σ-Bond; 3. η5-Cyclopentadienyl Molybdenum Complexes
  • 3.1. η5-Cyclopentadienyl molybdenum complexes bearing a halide or alkyl ligand3.2. Chiral organomolybdenum complexes; 3.3. Ansa-bridged η5-cyclopentadienyl molybdenum complexes; 3.4. Dinuclear η5-cyclopentadienyl molybdenum complexes; 3.5. η5-Cyclopentadienyl molybdenum complexes with NHC spectator ligands; 3.6. η5-Cyclopentadienyl molybdenum complexes with a π-allyl ligand; 4. Summary and Outlook; References; Chapter Three: Manganese and Iron Bleaching and Oxidation Catalysts; 1. Introduction; 2. Epoxidation of Alkenes; 2.1. General
  • 2.2. Manganese complexes containing 1,4,7-trimethyl-1,4,7-triazacyclononane ligands3. Cellulosic Bleaching; 3.1. Detergent applications; 3.1.1. General; 3.1.2. Activation of hydrogen peroxide by transition-metal complexes; 3.1.3. Stain bleaching by manganese complexes with 1,4,7-triazacyclononane-based ligands; 3.2. Raw cotton bleaching; 3.2.1. General; 3.2.2. Manganese complexes containing 1,4,7-triazacyclononane ligands; 3.3. Wood pulp bleaching; 3.3.1. General; 3.3.2. Bleach catalysts; 4. Paint Drying; 5. Conclusions; References
  • Chapter Four: Green Challenges of Catalysis via Iron(IV)oxo and Iron(V)oxo Species1. Introduction; 2. Iron(IV)oxo Complexes; 3. A Race for Iron(V)oxo Molecules; 3.1. Spectral characterization of iron(V)oxo compounds; 3.2. Reactivity of iron(V)oxo complexes; 4. Oxidative Catalysis in Aqueous Environment; 4.1. Guiding strategies; 4.2. Catalyzed oxidations by hydrogen peroxide in water; 4.3. Second generation of TAML activators; 4.4. Problems associated with environmentally relevant catalysis; 4.5. Novel applications of TAML activators
  • 5. Back to Nature or Metal-Organic Framework Instead of a Protein Coat?5.1. Protection of oxidation catalyst by biomolecules; 5.2. Metal-organic materials; 6. Concluding Remarks; Acknowledgments; References; Chapter Five: Manganese Compounds as Versatile Catalysts for the Oxidative Degradation of Organic Dyes; 1. Introduction; 2. Metal Ion-Catalyzed Oxidative Dye Degradation by H2O2; 2.1. General observations; 2.2. Complex formation between bicarbonate and Mn(II); 2.3. Complex formation between dye and Mn(II); 2.4. Mn(II)+H2O2/HCO3-: Intermediates in the absence of dye substrate
  • 2.5. Kinetic investigations
Dimensions
unknown
Extent
1 online resource (341 p.)
Form of item
online
Isbn
9780124046405
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (EBL)1111845
  • (OCoLC)827210726
  • (SSID)ssj0000912399
  • (PQKBManifestationID)11554271
  • (PQKBTitleCode)TC0000912399
  • (PQKBWorkID)11006024
  • (PQKB)10862386
  • (MiAaPQ)EBC1111845
  • (EXLCZ)992670000000325410

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