The Resource Assessing the functional structure of molecular transporters by EPR spectroscopy, Matthias J. N. Junk, (electronic resource)

Assessing the functional structure of molecular transporters by EPR spectroscopy, Matthias J. N. Junk, (electronic resource)

Label
Assessing the functional structure of molecular transporters by EPR spectroscopy
Title
Assessing the functional structure of molecular transporters by EPR spectroscopy
Statement of responsibility
Matthias J. N. Junk
Creator
Contributor
Provider
Subject
Language
eng
Summary
In his thesis, Matthias Junk takes an innovative approach to assess the local structure and dynamics of biological and synthetic amphiphilic macromolecules capable of transporting small molecules. Replacing the latter with stable radicals, he uses state-of-the-art electron paramagnetic resonance (EPR) spectroscopy to describe the highly relevant transport function from the viewpoint of the guest molecules. Such, he demonstrates that the functional structure of human serum albumin in solution significantly differs from its crystal structure – a consequence of the protein’s adaptability to host various endogenous compounds and drug molecules. Further, he shows that the thermal collapse of thermoresponsive hydrogels and dendronized polymers leads to static and dynamic heterogeneities on the nanoscale. These heterogeneities bear consequences for the material’s hosting properties and enable unforeseen complex catalytic functionalities
Member of
Cataloging source
GW5XE
http://library.link/vocab/creatorName
Junk, Matthias J. N
Dissertation note
Thesis (PhD.)-- Johannes Gutenberg-Universität Mainz.
Image bit depth
0
LC call number
QD96.E4
LC item number
J86 2012
Literary form
non fiction
Nature of contents
dictionaries
http://library.link/vocab/relatedWorkOrContributorName
SpringerLink
Series statement
Springer Theses
http://library.link/vocab/subjectName
  • Electron paramagnetic resonance spectroscopy
  • Molecule-molecule collisions
  • Electron paramagnetic resonance spectroscopy
  • Molecule-molecule collisions
  • Science des matériaux
  • Chimie
Label
Assessing the functional structure of molecular transporters by EPR spectroscopy, Matthias J. N. Junk, (electronic resource)
Instantiates
Publication
Note
"Doctoral thesis accepted by Johannes Gutenberg-Universität Mainz, Mainz, Germany."--T.p
Antecedent source
mixed
Bibliography note
Includes bibliographical references
Color
not applicable
Contents
Electron Paramagnetic Resonance Theory -- The Functional Structure of Human Serum Albumin -- Copper Complexes of Star-Shaped Cholic Acid Oligomers with 1,2,3-Triazole Moieties -- Nano-Inhomogeneities in Structure and Reactivity of Thermoresponsive Hydrogels -- Thermoresponsive Spin-Labeled Hydrogels as Separable DNP Polarizing Agents -- Local Nanoscopic Heterogeneities in Thermoresponsive Dendronized Polymers
Dimensions
unknown
Extent
1 online resource (xvi, 212 p.)
File format
multiple file formats
Form of item
  • online
  • electronic
Isbn
9783642251351
Level of compression
uncompressed
Other physical details
ill.
Quality assurance targets
absent
Reformatting quality
access
Specific material designation
remote
System control number
  • (OCoLC)773283729
  • (OCoLC)ocn773283729
Label
Assessing the functional structure of molecular transporters by EPR spectroscopy, Matthias J. N. Junk, (electronic resource)
Publication
Note
"Doctoral thesis accepted by Johannes Gutenberg-Universität Mainz, Mainz, Germany."--T.p
Antecedent source
mixed
Bibliography note
Includes bibliographical references
Color
not applicable
Contents
Electron Paramagnetic Resonance Theory -- The Functional Structure of Human Serum Albumin -- Copper Complexes of Star-Shaped Cholic Acid Oligomers with 1,2,3-Triazole Moieties -- Nano-Inhomogeneities in Structure and Reactivity of Thermoresponsive Hydrogels -- Thermoresponsive Spin-Labeled Hydrogels as Separable DNP Polarizing Agents -- Local Nanoscopic Heterogeneities in Thermoresponsive Dendronized Polymers
Dimensions
unknown
Extent
1 online resource (xvi, 212 p.)
File format
multiple file formats
Form of item
  • online
  • electronic
Isbn
9783642251351
Level of compression
uncompressed
Other physical details
ill.
Quality assurance targets
absent
Reformatting quality
access
Specific material designation
remote
System control number
  • (OCoLC)773283729
  • (OCoLC)ocn773283729

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