The Resource Relaxometry of water-metal ion interactions, edited by Rudi van Eldik, Ivano Bertini, (electronic resource)

Relaxometry of water-metal ion interactions, edited by Rudi van Eldik, Ivano Bertini, (electronic resource)

Label
Relaxometry of water-metal ion interactions
Title
Relaxometry of water-metal ion interactions
Statement of responsibility
edited by Rudi van Eldik, Ivano Bertini
Contributor
Subject
Genre
Language
  • eng
  • eng
Summary
Water interacts with metal ions in a variety of contexts: from aqueous solutions of inorganic salts to enzymatic catalysis. The investigation of water-metal ion interactions is conveniently performed through water 1H NMR at different magnetic field-a technique known as relaxometry. Advances in Inorganic Chemistry, Volume 57 focuses on relaxometry of water-metal ion interactions.Contributions by leading experts in the field cover important advances in inorganic and bioinorganic chemistry; another welcomed addition to the widely acclaimed series, Advances in Inorganic Chemistry
Member of
Is Subseries of
Cataloging source
MiAaPQ
Dewey number
  • 546
  • 546/.05
Illustrations
illustrations
Index
index present
Language note
English
LC call number
QD151
LC item number
.R45 2005
Literary form
non fiction
Nature of contents
  • dictionaries
  • bibliography
http://library.link/vocab/relatedWorkOrContributorName
  • Eldik, Rudi van
  • Bertini, Ivano
Series statement
Advances in inorganic chemistry
Series volume
57
http://library.link/vocab/subjectName
  • Chemistry, Inorganic
  • Ions
Label
Relaxometry of water-metal ion interactions, edited by Rudi van Eldik, Ivano Bertini, (electronic resource)
Instantiates
Publication
Note
Description based upon print version of record
Bibliography note
Includes bibliographical references and index
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Cover; ADVISORY BOARD; copyright; table of contents; PREFACE; ERRATUM; INTRODUCTION: GENERAL THEORY OF NUCLEAR RELAXATION; I. What is Nuclear Relaxation?; A. LONGITUDINAL RELAXATION; B. TRANSVERSE RELAXATION; C. THE ROTATING FRAME ...; D. CROSS-RELAXATION ...; E. CROSS-CORRELATION ...; II. Relaxation Mechanisms; A. INTERACTION WITH RAN...; B. RELAXATION BY CHEMIC...; C. SCALAR RELAXATION OF ...; D. RELAXATION BY DIPOLAR...; E. QUADRUPOLAR RELAX...; III. Water NMRD in Diamagnetic Systems; A. PUREWATER; B. WATER IN PROTEIN SOL...; REFERENCES 1
  • NMR RELAXATION IN SOLUTION OF PARAMAGNETIC COMPLEXES:RECENT THEORETICAL PROGRESS FOR S=1I. Introduction; II. The ''Classical'' Theory; A. THE SOLOMON^BLOEMB...; B. THE MODIFIED SOLOMON...; C. VALIDITY OF THE POINT-...; D. THE REDFIELD RELAX...; III. The Curie-Spin Relaxation and Related Topics; A. THE CURIE-SPIN RELAX...; B. PARAMAGNETIC CROSS...; IV. The General (Slow-Motion) Theory; A. THE REDFIELD LIMIT AND ...; B. THE LATTICE AND THE ZFS; C. THE EFFECTS OF ZFS ...; V. Electron Spin Relaxation and the PRE in Some Limiting Cases; A. HIGHLY SYMMETRIC SYS...; B. SLOWLY-ROTATING, LOW..
  • C. RAPIDLY-ROTATING SYS...D. ELECTRON SPIN DYNA...; VI. Spin-Dynamics Models; VII. Outer-Sphere Relaxation; A. GENERAL ASPECTS; B. OUTER-SPHERE PRE AND...; C. OUTER-SPHERE RELAX...; D. CHEMICAL EXCHANGE; VIII. Molecular Vibrations, Electron Spin Relaxation and the PRE; IX. Concluding Remarks; ACKNOWLEDGMENTS 2; REFERENCES 2; 1H NMRD PROFILES OF PARAMAGNETIC COMPLEXES AND METALLOPROTEINS; I. From the NMRD Profile to the Electron Relaxation Mechanism; A. DEPENDENCE OF THE ...; B. THE ORIGIN OF ELECT...; C. ELECTRON RELAXATION ..
  • II. From the NMRD Profile to the Structural and Dynamic ParametersA. DEPENDENCE OF THE ...; B. COPPER COMPLEXES ...; C. IRON COMPLEXES AND ...; D. MANGANESE COMPLEX...; E. OTHER TRANSITION...; F. GADOLINIUM COMPLEXES...; III. Magnetic Coupled Systems; A. NUCLEAR AND ELECT...; B. EXAMPLES; IV. Conclusions; ACKNOWLEDGMENTS 3; REFERENCES 3; Gd(III)-BASED CONTRAST AGENTS FOR MRI; I. General Remarks; II. Contributions to the Relaxivity; A. INNER-SPHERE CONTRI...; B. OUTER-SPHERE CONTRI...; C. SECOND-SPHERE CONTR...; III. Relevant Parameters in Fitting the NMRD Profiles of Contrast Agents
  • A. THE HYDRATION NUMBER qB. THE Gd^H DISTANCE rH; C. THE ROTATIONAL CORRE...; D. THE EXCHANGE CORRE...; E. THE ELECTRON SPIN ...; IV. Methods for Improving Relaxivity; A. INCREASE OF THE HYD...; B. LENGTHENING OF tR; C. OPTIMIZATION OF tM; V. Responsive Contrast Agents; A. pH SENSITIVE; B. TEMPERATURE SENSITIVE; C. AGENTS SENSITIVE TO ...; D. ENZYME RESPONSIVE; E. AGENTS SENSITIVE TO ...; VI. Insights for Molecular Imaging Applications; VII. Final Remarks; REFERENCES 4; RELAXATION BY METAL-CONTAINING NANOSYSTEMS; I. Super-Paramagnetic Particles; A. INTRODUCTION; B. PHENOMENOLOGICAL ..
  • C. HIGH ANISOTROPYMODEL
Dimensions
unknown
Extent
1 online resource (496 p.)
Form of item
online
Isbn
9781280633188
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (EBL)269639
  • (OCoLC)475998381
  • (SSID)ssj0000356329
  • (PQKBManifestationID)12102967
  • (PQKBTitleCode)TC0000356329
  • (PQKBWorkID)10349515
  • (PQKB)11785924
  • (MiAaPQ)EBC269639
  • (EXLCZ)991000000000364888
Label
Relaxometry of water-metal ion interactions, edited by Rudi van Eldik, Ivano Bertini, (electronic resource)
Publication
Note
Description based upon print version of record
Bibliography note
Includes bibliographical references and index
Carrier category
online resource
Carrier category code
cr
Content category
text
Content type code
txt
Contents
  • Cover; ADVISORY BOARD; copyright; table of contents; PREFACE; ERRATUM; INTRODUCTION: GENERAL THEORY OF NUCLEAR RELAXATION; I. What is Nuclear Relaxation?; A. LONGITUDINAL RELAXATION; B. TRANSVERSE RELAXATION; C. THE ROTATING FRAME ...; D. CROSS-RELAXATION ...; E. CROSS-CORRELATION ...; II. Relaxation Mechanisms; A. INTERACTION WITH RAN...; B. RELAXATION BY CHEMIC...; C. SCALAR RELAXATION OF ...; D. RELAXATION BY DIPOLAR...; E. QUADRUPOLAR RELAX...; III. Water NMRD in Diamagnetic Systems; A. PUREWATER; B. WATER IN PROTEIN SOL...; REFERENCES 1
  • NMR RELAXATION IN SOLUTION OF PARAMAGNETIC COMPLEXES:RECENT THEORETICAL PROGRESS FOR S=1I. Introduction; II. The ''Classical'' Theory; A. THE SOLOMON^BLOEMB...; B. THE MODIFIED SOLOMON...; C. VALIDITY OF THE POINT-...; D. THE REDFIELD RELAX...; III. The Curie-Spin Relaxation and Related Topics; A. THE CURIE-SPIN RELAX...; B. PARAMAGNETIC CROSS...; IV. The General (Slow-Motion) Theory; A. THE REDFIELD LIMIT AND ...; B. THE LATTICE AND THE ZFS; C. THE EFFECTS OF ZFS ...; V. Electron Spin Relaxation and the PRE in Some Limiting Cases; A. HIGHLY SYMMETRIC SYS...; B. SLOWLY-ROTATING, LOW..
  • C. RAPIDLY-ROTATING SYS...D. ELECTRON SPIN DYNA...; VI. Spin-Dynamics Models; VII. Outer-Sphere Relaxation; A. GENERAL ASPECTS; B. OUTER-SPHERE PRE AND...; C. OUTER-SPHERE RELAX...; D. CHEMICAL EXCHANGE; VIII. Molecular Vibrations, Electron Spin Relaxation and the PRE; IX. Concluding Remarks; ACKNOWLEDGMENTS 2; REFERENCES 2; 1H NMRD PROFILES OF PARAMAGNETIC COMPLEXES AND METALLOPROTEINS; I. From the NMRD Profile to the Electron Relaxation Mechanism; A. DEPENDENCE OF THE ...; B. THE ORIGIN OF ELECT...; C. ELECTRON RELAXATION ..
  • II. From the NMRD Profile to the Structural and Dynamic ParametersA. DEPENDENCE OF THE ...; B. COPPER COMPLEXES ...; C. IRON COMPLEXES AND ...; D. MANGANESE COMPLEX...; E. OTHER TRANSITION...; F. GADOLINIUM COMPLEXES...; III. Magnetic Coupled Systems; A. NUCLEAR AND ELECT...; B. EXAMPLES; IV. Conclusions; ACKNOWLEDGMENTS 3; REFERENCES 3; Gd(III)-BASED CONTRAST AGENTS FOR MRI; I. General Remarks; II. Contributions to the Relaxivity; A. INNER-SPHERE CONTRI...; B. OUTER-SPHERE CONTRI...; C. SECOND-SPHERE CONTR...; III. Relevant Parameters in Fitting the NMRD Profiles of Contrast Agents
  • A. THE HYDRATION NUMBER qB. THE Gd^H DISTANCE rH; C. THE ROTATIONAL CORRE...; D. THE EXCHANGE CORRE...; E. THE ELECTRON SPIN ...; IV. Methods for Improving Relaxivity; A. INCREASE OF THE HYD...; B. LENGTHENING OF tR; C. OPTIMIZATION OF tM; V. Responsive Contrast Agents; A. pH SENSITIVE; B. TEMPERATURE SENSITIVE; C. AGENTS SENSITIVE TO ...; D. ENZYME RESPONSIVE; E. AGENTS SENSITIVE TO ...; VI. Insights for Molecular Imaging Applications; VII. Final Remarks; REFERENCES 4; RELAXATION BY METAL-CONTAINING NANOSYSTEMS; I. Super-Paramagnetic Particles; A. INTRODUCTION; B. PHENOMENOLOGICAL ..
  • C. HIGH ANISOTROPYMODEL
Dimensions
unknown
Extent
1 online resource (496 p.)
Form of item
online
Isbn
9781280633188
Media category
computer
Media type code
c
Specific material designation
remote
System control number
  • (EBL)269639
  • (OCoLC)475998381
  • (SSID)ssj0000356329
  • (PQKBManifestationID)12102967
  • (PQKBTitleCode)TC0000356329
  • (PQKBWorkID)10349515
  • (PQKB)11785924
  • (MiAaPQ)EBC269639
  • (EXLCZ)991000000000364888

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