The Resource The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, by Lina K. Blusch, (electronic resource)

The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, by Lina K. Blusch, (electronic resource)

Label
The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist
Title
The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist
Statement of responsibility
by Lina K. Blusch
Creator
Contributor
Author
Provider
Subject
Language
eng
Summary
This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications
Member of
http://library.link/vocab/creatorName
Blusch, Lina K
Image bit depth
0
LC call number
QD146-197
Literary form
non fiction
http://library.link/vocab/relatedWorkOrContributorName
SpringerLink
Series statement
Springer Theses, Recognizing Outstanding Ph.D. Research,
http://library.link/vocab/subjectName
  • Chemistry
  • Chemistry, inorganic
  • Bioorganic chemistry
  • Chemistry, Organic
  • Chemistry
  • Inorganic Chemistry
  • Bioorganic Chemistry
  • Organometallic Chemistry
Label
The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, by Lina K. Blusch, (electronic resource)
Instantiates
Publication
Antecedent source
mixed
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
not applicable
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
General Introduction -- Objective -- Route to the Siamese-Twin Porphyrin -- Siamese-Twin Porphyrin LH4 -- Nickel and Copper Complexes -- Redox Properties -- Summary and Outlook -- Experimental Section -- APENDIX: Crystallographic Details -- Details on DFT calculations
Dimensions
unknown
Extent
XVIII, 158 p. 142 illus., 48 illus. in color.
File format
multiple file formats
Form of item
electronic
Isbn
9783319016740
Level of compression
uncompressed
Media category
computer
Media MARC source
rdamedia
Media type code
c
Other control number
10.1007/978-3-319-01674-0
Other physical details
online resource.
Quality assurance targets
absent
Reformatting quality
access
Specific material designation
remote
System control number
(DE-He213)978-3-319-01674-0
Label
The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist, by Lina K. Blusch, (electronic resource)
Publication
Antecedent source
mixed
Carrier category
online resource
Carrier category code
cr
Carrier MARC source
rdacarrier
Color
not applicable
Content category
text
Content type code
txt
Content type MARC source
rdacontent
Contents
General Introduction -- Objective -- Route to the Siamese-Twin Porphyrin -- Siamese-Twin Porphyrin LH4 -- Nickel and Copper Complexes -- Redox Properties -- Summary and Outlook -- Experimental Section -- APENDIX: Crystallographic Details -- Details on DFT calculations
Dimensions
unknown
Extent
XVIII, 158 p. 142 illus., 48 illus. in color.
File format
multiple file formats
Form of item
electronic
Isbn
9783319016740
Level of compression
uncompressed
Media category
computer
Media MARC source
rdamedia
Media type code
c
Other control number
10.1007/978-3-319-01674-0
Other physical details
online resource.
Quality assurance targets
absent
Reformatting quality
access
Specific material designation
remote
System control number
(DE-He213)978-3-319-01674-0

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